1. 毕业设计（论文）的内容和要求

内容：探究al/ mg合金沉积形成水滑石的合成方法及其形貌控制。

探究ph、尿素等因素对合成产物形貌的影响、 要求： 需要本科生对al/ mg合金沉积形成水滑石的制备方法有一个比较系统的认识，同时能独立的完成实验。

需要本科生能够逻辑性的分析整个合成制备与催化反应的过程。

2. 参考文献

[1] K. Xia, W.-Z. Lang, P.P. Li, L.L. Long, X. Yan, Y.J. Guo, The influences of Mg/Al molar ratio on the properties of PtIn/Mg(Al)O-x catalysts for propane dehydrogenation reaction, Chem. Eng. J. 284 (2016) 1068. [2] K. Xia, W.Z. Lang, P.P. Li, X. Yan, Y.J. Guo, Analysis of the catalytic activity induction and deactivation of PtIn/Mg(Al)O catalysts for propane dehydrogenation reaction, RSC Adv. 5 (2015) 64689. [3] J.J. Shi, Y.M. Zhou, Y.W. Zhang, S.J. Zhou, Z.W. Zhang, J. Kong, M.P. Guo, Synthesis of magnesium-modified mesoporous Al 2 O 3 with enhanced catalytic performance for propane dehydrogenation, J. Mater. Sci. 49 (2014) 5772. [4] A.D. Qiu, E.X. Li, Y.N. Fan, Effect of support composition on catalytic performance of PtSn/ZSM-5 catalyst for propane dehydrogenation, Chinese J. Catal. 28 (2007) 970. [5] N.I. Kuznetsova, G.Y. Popova, L.I. Kuznetsova, V.I. Zaikovskii, S.V. Koscheev, Y.A. Chesalov, T.V. Andrushkevich, A.S. Lisitsyn, V.A. Likholobov, S. Han, Selective dehydrogenation of propane to propene with O 2 #8211;H 2 on bifunctional Pt- H3PMo12O40 catalysts, Appl. Catal. A Gen. 477 (2014) 1. [6] D.L. Hoang, S.A.F. Farrage, J. Radnik, M.M. Pohl, M. Schneider, H. Lieske, A. Martin, A comparative study of zirconia and alumina supported Pt and Pt#8211;Sn catalysts used for dehydrocyclization of n-octane, Appl. Catal. A Gen. 333 (2007) 67. [7] S.A. Bocanegra, A. Guerrero-Ruiz, S.R. de Miguel, O.A. Scelza, Performance of PtSn catalysts supported on MAl 2 O 4 (M: Mg or Zn) in n-butane dehydrogenation: characterization of the metallic phase, Appl. Catal. A Gen. 277 (2004) 11. [8] B.J. Xu, B. Zheng, W.M. Hua, Y.H. Yue, Z. Gao, Support effect in dehydrogenation of propane in the presence Of CO 2 over supported gallium oxide catalysts, J. Catal. 239 (2006) 470. [9] P. Sun, G. Siddiqi, M. Chi, A.T. Bell, Synthesis and characterization of a new catalyst Pt/Mg(Ga)(Al)O for alkane dehydrogenation, J. Catal. 274 (2010) 192. [10] G. Siddiqi, P. Sun, V. Galvita, A.T. Bell, Catalyst performance of novel Pt/Mg(Ga) (Al)O catalysts for alkane dehydrogenation, J. Catal. 274 (2010) 200. [11] J.H. Kwak, J.Z. Hu, D. Mei, C.W. Yi, D.H. Kim, C.H.F. Peden, L.F. Allard, J. Szanyi, Coordinatively unsaturated Al 3 centers as binding sites for active catalyst phases of platinum on gamma-Al 2 O 3 , Science 325 (2009) 1670. [12] K. Hosni, O. Abdelkarim, N. Frini-Srasra, E. Srasra, Synthesis, structure and photocatalytic activity of calcined Mg#8211;Al#8211;Ti-layered double hydroxides, Korean J. Chem. Eng. 32 (2015) 104. [13] J. Zhu, M.L. Yang, Y. Yu, Y.A. Zhu, Z.J. Sui, X.G. Zhou, A. Holmen, D. Chen, Size- dependent reaction mechanism and kinetics for propane dehydrogenation over Pt catalysts, ACS Catal. 5 (2015) 6310. [14] X.B. Zhang, L. Zhong, Q.H. Guo, H. Fan, H.Y. Zheng, K.C. Xie, Influence of the calcination on the activity and stability of the Cu/ZnO/Al 2 O 3 catalyst in liquid phase methanol synthesis, Fuel 89 (2010) 1348. [15] J.H. Flores, M.I.P. da Silva, Acid properties of the hybrid catalyst CuO#8211;ZnO or CuO#8211;ZnO#8211;Al 2 O 3 /H-: an infrared study, Colloids Surf. A 322 (2008) 113. [16] A. Bienholz, F. Schwab, P. Claus, Hydrogenolysis of glycerol over a highly active CuO/ZnO catalyst prepared by an oxalate gel method: influence of solvent and reaction temperature on catalyst deactivation, Green Chem. 12 (2010) 290. [17] Z. Mosayebi, M. Rezaei, N. Hadian, F.Z. Kordshuli, F. Meshkani, Low temperature synthesis of nanocrystalline magnesium aluminate with high surface area by surfactant assisted precipitation method: effect of preparation conditions, Mater. Res. Bull. 47 (2012) 2154.

3. 毕业设计（论文）进程安排

2017-02-24#8212;03-10 查阅国内外有关文献，拟订 2017-03-10#8212;03-20 翻译外文文献，并撰写文献综述。

2017-03-20#8212;04-10 按照拟定的实验方案依次进行实验。

2017-04-10#8212;04-30 处理试验数据，分析结果。