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毕业论文网 > 任务书 > 材料类 > 高分子材料与工程 > 正文

碳化自缩聚多孔有机聚合物的催化应用任务书

 2020-06-29 08:06  

1. 毕业设计(论文)的内容和要求

毕业论文是对大学四年学习情况以及对所做的课题情况的反映,其内容应该包括: a) 查阅相关文献资料,提出实验计划,明确实验内容。

b) 写出文献综述,了解本课题最新研究进展 c) 认真实验,确定最佳工艺条件。

通过实验研究自缩聚多孔有机聚合物及其碳化材料的合成方法,并研究以其为基体材料负载贵金属催化剂对4-硝基苯酚催化性能的影响。

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2. 参考文献

[1] Rathod M K, Banerjee J. Thermal stability of phase change materials used in latent heat energy storage systems: A review [J]. Renewable and Sustainable Energy Reviews, 2013, 18: 246-258. [2] Li M, Wu Z. A review of intercalation composite phase change material: Preparation, structure and properties [J]. Renewable and Sustainable Energy Reviews, 2012, 16: 2094-2101. [3] Yang D, Shi S, Xiong L, et al. Paraffin/Palygorskite composite phase change materials for thermal energy storage [J]. Solar Energy Materials and Solar Cells, 2016, 144: 228-234. [4] Wi S, Seo J, Jeong S-G, et al. Thermal properties of shape-stabilized phase change materials using fatty acid ester and exfoliated graphite nanoplatelets for saving energy in buildings [J]. Solar Energy Materials and Solar Cells, 2015, 143: 168-173. [5] Goitandia A M, Beobide G, Aranzabe E, et al. Development of content-stable phase change composites by infiltration into inorganic porous supports [J]. Solar Energy Materials and Solar Cells, 2015, 134: 318-328. [6] Zhang D, Tian S, Xiao D. Experimental study on the phase change behavior of phase change material confined in pores [J]. Solar Energy, 2007, 81: 653-660. [7] Zalb, Mar N J M, Cabeza L F, et al. Review on thermal energy storage with phase change: materials, heat transfer analysis and applications [J]. Applied Thermal Engineering, 2003, 23: 251-283. [8] Nomura T, Okinaka, Akiyama T. Impregnation of porous material with phase change material for thermal energy storage [J]. Materials Chemistry and Physics, 2009, 115: 846-850. [9] Ye S, Zhang Q, Hu D, et al. Core-shell-like structured graphene aerogel encapsulating paraffin: shape-stable phase change material for thermal energy storage [J]. J Mater Chem A, 2015, 3: 4018-4025. [10] Liang W, Zhang G, Sun H, et al. Conjugated microporous polymers/n-carboxylic acids composites as form-stable phase change materials for thermal energy storage [J]. Rsc Advances, 2013, 3: 18022-18027. [11] Huang X, Xia W, Zou R. Nanoconfinement of phase change materials within carbon aerogels: phase transition behaviours and photo-to-thermal energy storage [J]. J Mater Chem A, 2014, 2: 19963-19968. [12] AkhianiA R, Mehrali M, Tahan Latibari S, et al. One-Step Preparation of Form-Stable Phase Change Material through Self-Assembly of Fatty Acid and Graphene [J]. The Journal of Physical Chemistry C, 2015, 119: 22787-22796. [13] Feczk T, Trif L, Hor K D. Latent heat storage by silica-coated polymer beads containing organic phase change materials [J]. Solar Energy, 2016, 132: 405-414. [14] Wang S, Tan L, Zhang C, et al. Novel POSS-based organic-inorganic hybrid porous materials by low cost strategies [J]. J Mater Chem A, 2015, 3: 6542-6548. [15] Li B, Yang X, Xia L, et al. Hollow microporous organic capsules [J]. Scientific reports, 2013, 3:21-28. [16] Li H, Meng B, Chai S-H, et al. Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption- facilitated molecular catalyst support for transformation of water-soluble aromatic molecules [J]. Chem Sci, 2016, 7: 905-909.

3. 毕业设计(论文)进程安排

2017.12~2018.1 检索国内外相关文献和专著,了解微孔聚合物的研究进展,初步选定原料及反应条件,制定实验初步方案。

2018.1~2018.3 合成自缩聚微孔聚合物,并对其结构和性能进行表征和分析,对实验方案进行改进。

将材料进行碳化制备碳化材料。

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