可编程温度响应智能水凝胶制动器的设计与制备开题报告
2020-04-10 02:04
1. 研究目的与意义（文献综述）
1.1 目的及意义
水凝胶是一种经适度交联而具有三维网络的、亲水但不溶于水的功能高分子材料[1]。智能水凝胶[2-4]，又称刺激响应水凝胶，是一类能对外界环境变化具有响应性的水凝胶，其在外界环境刺激因素（包括温度[5-7]、光[8-10]、电磁场[11-13]和溶剂[14; 15]等）影响下，能产生有效响应，使自身的性质（如相态、形状、力学性能[16]等）随之发生变化，如图1（a）、（b）、（c）所示为智能响应性水凝胶实现跨结构尺度变化。
近年来，基于响应性水凝胶材料的各种功能性器件在智能微机械[17-19]、软体机器人[20-22]及生物医学等领域广泛应用。将刺激响应性水凝胶材料同惰性材料相结合，控制不同材料按照特定的图案进行排布，在外界环境刺激下，水凝胶材料会响应环境刺激溶胀或收缩，而惰性材料保持不变，这种复合结构就能够按照设定的图案进行响应性形变。按照这一思路，各种水凝胶自折叠致动器结构[23-25]、折纸结构[26-28]被不断报道，如图2（a）、（b）所示为响应性水凝胶致动器的应用。
2. 研究的基本内容与方案
2.1 研究（设计）的基本内容
1）根据文献调研响应性水凝胶的研究现状，详细了解响应性水凝胶的工作原理和应用形式，对掺杂纳米材料和多响应机制深入理解。
2）激光修饰衬底薄膜工艺的研究。通过激光修饰衬底材料将其制作为所需要的形状。激光剪裁工艺需要考虑薄膜的厚度、物理性质，以及对热量的吸收程度，为之相关的是激光参数，包括激光波长、重复频率、激光功率和脉冲宽度。
3. 研究计划与安排
第1-2周:完成文献调研；
第3周:完成外文翻译；
第4周:完成开题报告；
4. 参考文献（12篇以上）
| [1] 李贤真, 李彦锋, 朱晓夏, et al. 高分子水凝胶材料研究进展[J]. 功能材料, 2003, 34(4): 382-385. [2] Zhang Y S, Khademhosseini A. Advances in engineering hydrogels[J]. Science, 2017, 356(6337): eaaf3627. [3] Gladman A S, Matsumoto E A, Nuzzo R G, et al. Biomimetic 4D printing[J]. Nature materials, 2016, 15(4): 413-418. [4] Tibbits S. 4D printing: multi‐material shape change[J]. Architectural Design, 2014, 84(1): 116-121. [5] Zhang X, Pint C L, Lee M H, et al. Optically-and thermally-responsive programmable materials based on carbon nanotube-hydrogel polymer composites[J]. Nano letters, 2011, 11(8): 3239-3244. [6] Davis D, Chen B, Dickey M D, et al. Self-folding of thick polymer sheets using gradients of heat[J]. Journal of Mechanisms and Robotics, 2016, 8(3): 031014. [7] Yamamoto Y, Kanao K, Arie T, et al. Air ambient-operated pNIPAM-based flexible actuators stimulated by human body temperature and sunlight[J]. ACS applied materials amp; interfaces, 2015, 7(20): 11002-11006. [8] Liu Y, Boyles J K, Genzer J, et al. Self-folding of polymer sheets using local light absorption[J]. Soft Matter, 2012, 8(6): 1764-1769. [9] Ryu J, D’amato M, Cui X, et al. Photo-origami—Bending and folding polymers with light[J]. Applied Physics Letters, 2012, 100(16): 161908. [10] Tai Y, Lubineau G, Yang Z. Light‐Activated Rapid‐Response Polyvinylidene‐Fluoride‐Based Flexible Films[J]. Advanced Materials, 2016, 28(23): 4665-4670. [11] Hu W, Lum G Z, Mastrangeli M, et al. Small-scale soft-bodied robot with multimodal locomotion[J]. Nature, 2018. [12] Breger J C, Yoon C, Xiao R, et al. Self-folding thermo-magnetically responsive soft microgrippers[J]. ACS applied materials amp; interfaces, 2015, 7(5): 3398-3405. [13] Lum G Z, Ye Z, Dong X, et al. Shape-programmable magnetic soft matter[J]. Proceedings of the National Academy of Sciences, 2016, 113(41): E6007-E6015. [14] Han D D, Zhang Y L, Jiang H B, et al. Moisture‐responsive graphene paper prepared by self‐controlled photoreduction[J]. Advanced Materials, 2015, 27(2): 332-338. [15] Luo C, Yeh C N, Baltazar J M L, et al. A Cut‐and‐Paste Approach to 3D Graphene‐Oxide‐Based Architectures[J]. Advanced Materials, 2018. [16] Sun J-Y, Zhao X, Illeperuma W R, et al. Highly stretchable and tough hydrogels[J]. Nature, 2012, 489(7414): 133. [17] Felton S, Tolley M, Demaine E, et al. A method for building self-folding machines[J]. Science, 2014, 345(6197): 644-646. [18] Wehner M, Truby R L, Fitzgerald D J, et al. An integrated design and fabrication strategy for entirely soft, autonomous robots[J]. Nature, 2016, 536(7617): 451-455. [19] Duduta M, Clarke D R, Wood R J. A high speed soft robot based on dielectric elastomer actuators[C]. Robotics and Automation (ICRA), 2017 IEEE International Conference on, 2017: 4346-4351. [20] Bartlett N W, Tolley M T, Overvelde J T, et al. A 3D-printed, functionally graded soft robot powered by combustion[J]. Science, 2015, 349(6244): 161-165. [21] Acome E, Mitchell S, Morrissey T, et al. Hydraulically amplified self-healing electrostatic actuators with muscle-like performance[J]. Science, 2018, 359(6371): 61-65. [22] Paik J. Soft Robotics: Transferring Theory to Application," Soft Components for Soft Robots"[R]. Springer, 2015. [23] Wang W, Kim N-G, Rodrigue H, et al. Modular assembly of soft deployable structures and robots[J]. Materials Horizons, 2017, 4(3): 367-376. [24] Van Manen T, Janbaz S, Zadpoor A A. Programming the shape-shifting of flat soft matter[J]. Materials Today, 2017. [25] Azam A, Laflin K E, Jamal M, et al. Self-folding micropatterned polymeric containers[J]. Biomedical microdevices, 2011, 13(1): 51-58. [26] Chen Y, Peng R, You Z. Origami of thick panels[J]. Science, 2015, 349(6246): 396-400. [27] Fu H, Nan K, Bai W, et al. Morphable 3D mesostructures and microelectronic devices by multistable buckling mechanics[J]. Nature materials, 2018, 17(3): 268. [28] Santangelo C D. Extreme Mechanics: Self-Folding Origami[J]. Annual Review of Condensed Matter Physics, 2017, 8: 165-183. [29] Wichterle O, Lim D. Hydrophilic gels for biological use[J]. Nature, 1960, 185(4706): 117. [30] Hirokawa Y, Tanaka T. Volume phase transition in a non‐ionic gel[C]. AIP Conference Proceedings, 1984: 203-208. [31] Pelton R, Chibante P. Preparation of aqueous latices with N-isopropylacrylamide[J]. Colloids and Surfaces, 1986, 20(3): 247-256. [32] Na J H, Evans A A, Bae J, et al. Programming reversibly self‐folding origami with micropatterned photo‐crosslinkable polymer trilayers[J]. Advanced Materials, 2015, 27(1): 79-85. [33] Zheng W J, An N, Yang J H, et al. Tough al-alginate/poly (n-isopropylacrylamide) hydrogel with tunable lcst for soft robotics[J]. ACS applied materials amp; interfaces, 2015, 7(3): 1758-1764. [34] Gultepe E, Randhawa J S, Kadam S, et al. Biopsy with Thermally‐Responsive Untethered Microtools[J]. Advanced materials, 2013, 25(4): 514-519. [35] Kim S Y, Cho S M, Lee Y M, et al. Thermo‐and pH‐responsive behaviors of graft copolymer and blend based on chitosan and N‐isopropylacrylamide[J]. Journal of Applied Polymer Science, 2000, 78(7): 1381-1391.
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