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毕业论文网 > 任务书 > 化学化工与生命科学类 > 应用化学 > 正文

咪唑类离子液体的合成及应用任务书

 2020-05-10 02:05  

1. 毕业设计(论文)的内容和要求

工业产品邻硝基氯苯往往含有噻吩及噻吩的衍生物。

这些含硫化合物不仅影响产品的质量,加剧设备的腐蚀,而且对环境和安全生产产生危害。

目前研究邻硝基氯苯脱硫的文献甚少,难点主要是催化过程中硝基和氯的保护。

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2. 参考文献

[1] Alain F. R.,Marc S.,Muriel R.,et al. Deep desulfurization of diesel feedstock by selective adsorption of refractory sulfur compounds[J]. Industrial and Engineering Chemistry Research,2008,47:9617-9622. [2]Arturo J H M,Ralph T Y. Desulfurization of diesel fuel by adsorption via π-complexation with vapor-phase exchanged Cu(I)-Y zeolites[J]. Journal of the American Chemical Society,2004,126(4):992-993. [3]mbalavanan J,Frances H Y,Ralph T Y. Effects of nitrogen compounds and polyaromatic hydrocarbons on desulfurization of liquid fuels by adsorption via π-complexation. Energy and Fuels,2006,20(3):909-914. [4]Wan Juan,Xu Fang,Xie Wei-jie,et al. The enhanced adsorption of dibenzothiophene onto cerium/nickel-exchanged zeolite Y[J]. Journal of Hazardous Materials,2009,163:538- 543. [5]周丹红,王玉清,贺宁,等. Cu(I),Ag(I)/分子筛化学吸附脱硫的π-络合机理[J]. 物理化学学报,2006,22(5):542-547. Zhou Dan -hong,Wang Yu -qing,He Ning,et al. The π - complexation mechanisms of Cu(I),Ag(I)/zeolites for desulfurization[J]. Acta Physico-Chimica Sinica,2006,22(5):542-547.(in Chinese) [6]Ralph T Y,Akira T,Frances H Y. New sorbents for desulfurization of liquid fuels by π-complexation[J]. Industrial and Engineering Chemistry Research,2001,40:6236-6239. [7]Akira T,Frances H Y,Ralph T Y. New sorbents for desulfurization by π-complexation:thiophene/benzene adsorption [J]. Industrial and Engineering Chemistry Research,2002,41(10):2487-2496. [8]Velu S,Ma Xiao -liang,Song Chun -shan. Selective adsorption for removing sulfur from jet fuel over zeolite-based adsorbents[J]. Industrial and Engineering Chemistry Re - search,2003,42(21):5293-5304. [9]Song Chun-shan, Ma Xiao-liang. New design approaches to ultra-clean diesel fuels by deep desulfurization and deep dearomatization[J]. Applied Catalysis B:Environmental,2003, 1(2):207-238. [10]查庆芳,高南星,李兆丰,等. 石油焦系活性炭的吸附脱硫 [J]. 燃料化学学报,2007,35(2):192-197. Zha Qing -fang,Gao Nan -xing,Li Zhao -feng,et al. Adsorption desulfurization by activated carbon from petroleum coke[J]. Journal of Fuel Chemistry and Technology,2007, 35(2):192-197.(in Chinese) [11]The Pritchard Corporation. Process for Desulfurization Gasoline and Hydrocarbon Feedstock[P]. US,5730860.1998. [12] Irvine R L,Benson B A,Varraveto D M. IRVAD Process- Low Cost Breakthrough for Low Sulfur Gasoline[R]. San Antonio,AM-99-42,1999. [13] Oil Gas Journal Editral Department. Phillips petroleum has stared up a new 6,000B/D unit at its burger,TEX,refinery[ J]. Oil and Gas Journal,2001,99(18):9. [14]Johnson B G,Slater P,Kidd D,et al. Application of Phillips's Zorb Process to Distillates-Meeting the Challenge[C]. New Orleans,AM-01-14,2001. [15]Ania C O,Bandosz T J. Metal-loaded polystyrene-based activated carbons as dibenzothiophene removal media via reactive adsorption[J]. Carbon,2006,44(12):2404-2412. [16] Bashkova Svetlana,Bagreev Andrey,Bandosz Teresa J. Catalytic properties of activated carbon surface in the process of adsorption/oxidation of methyl mercaptan[J]. Catalysis Today,2005,99(3-4):323-328. [17]Thomas Michel,Nicolaos Alexandre.Use of caesium-exchanged faujasite type zeolites for intense desulphurization of a gasoline cut:US,20060287192[P]. 2006-12-21. [18]Hern#225;ndez-Maldonado Arturo J,Yang Frances H,Qi Gongshin,et al.Desulfurization of transportation fuels by π-complexation sorbents: Cu(Ⅰ)-, Ni(Ⅱ)-, and Zn(Ⅱ)-zeolites[J]. Applied CatalysisB:Environmental,2005,56(1-2):111-126. [19] 杨永坛,王征,杨海鹰,等.几种汽油脱硫工艺中含硫化合物类型变化规律[J]. 石油与天然气化工,2004,33(5):336-339 [20]Larrubia Maria Angeles,Guti#232;rrez-Alejandre A#236;da,Ram#236;rez Jorge,et al.A FT-IR study of the adsorption of indole, carbazole,benzothiophene, dibenzothiophene and 4,6-dibenzothiophene over solid adsorbents and catalysts[J]. Applied Catalysis A:General,2002,224(1):167-178. [21]Zhang J C,Song L F,Hu Y J,et al. Investigation on gasoline deep desulfurization for fuel cell applications[J]. Energy Conversion and Management,2005,46(1):1-9. [22]Ramirez-Corredores M M,Hernandez Zaida,Guerra Julia,et al.Selective sulfur removal from hydrocarbon streams by adsorption:US,20050205470[P]. 2005-09-22. [23]Jeevanandam P,Klabunde K J,Tetzler S H. Adsorption of thiophenes out of hydrocarbons using metal impregnated nanocrystalline aluminum oxide[J]. Microporous and Mesoporous Materials,2005,79(1-3):101-110. [24]谷涛,慕旭宏,宗保宁. 磁稳定床中镍基非晶态合金汽油吸附脱 硫研究[J]. 石油学报:石油加工,2007,23(1):8-14. [25]王云芳,尹风利,史德青,等. 新型炭复合材料吸附剂脱除汽油 中硫化物的研究[J]. 石油炼制与化工,2006,37(6):37-40.

3. 毕业设计(论文)进程安排

2015.12.20-2016.1.16 查阅资料,完成开题报告。

2016.2.22-2016.3.2 确定方案,学习实验过程和操作。

2016.3.3-2016.5.20 制备离子液体并进行结构表征,进行脱硫实验 2016.5.21-2016.5.30 数据整理,撰写论文。

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