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毕业论文网 > 任务书 > 化学化工与生命科学类 > 应用化学 > 正文

新型双喹啉氮杂氟硼配合物的设计合成及其性能研究任务书

 2020-06-29 08:06  

1. 毕业设计(论文)的内容和要求

有机氟硼配合物具有较高的荧光量子效率,较强的吸收和荧光发射,良好的光稳定性以及化学可修饰性,在光电功能材料领域备受关注,已被广泛应用于分子探针、光动力学治疗、激光染料、非线性光学材料和太阳能电池等领域。

针对不同领域对有机发光材料的应用需求,从功能分子的设计合成入手,通过化学结构修饰来研究分子结构与光学性质之间的构效关系,对于开发性能优良的发光材料尤为重要,也可为多功能荧光分子的设计研发提供理论依据和实验基础。

在有机电致发光领域,红光和绿光发光材料研究较多,而高效蓝光材料的发展相对滞后。

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2. 参考文献

1. Burgess, A. L. a. K., BODIPY Dyes and Their Derivatives: Syntheses and Spectroscopic Properties. Chem. Rev. 2007, 107. 2. Zhu, X.; Huang, H.; Liu, R.; Jin, X.; Li, Y.; Wang, D.; Wang, Q.; Zhu, H., Aza-boron-diquinomethene complexes bearing N-aryl chromophores: synthesis, crystal structures, tunable photophysics, the protonation effect and their application as pH sensors. Journal of Materials Chemistry C 2015, 3 (15), 3774-3782. 3. Boens, N.; Leen, V.; Dehaen, W., Fluorescent indicators based on BODIPY. Chem Soc Rev 2012, 41 (3), 1130-72. 4. Jan K.; Lennart B.-A. J.; Leif S.; Tor N., Fluorescence and Absorption Spectroscopic Properties of Dipyrrometheneboron Difluoride (BODIPY) Derivatives in Liquids, Lipid Membranes, and Proteins. J . Am. Chem. Soc 1994, 116 (116). 5. Paolo Coppo, a. E. A. P. a. L. D. C., Tuning iridium(III) phenylpyridine complexes in the ”almost blue” region. Chem. .Commun 2004. 6. Kuei, C. Y.; Tsai, W. L.; Tong, B.; Jiao, M.; Lee, W. K.; Chi, Y.; Wu, C. C.; Liu, S. H.; Lee, G. H.; Chou, P. T., Bis-Tridentate Ir(III) Complexes with Nearly Unitary RGB Phosphorescence and Organic Light-Emitting Diodes with External Quantum Efficiency Exceeding 31%. Adv Mater 2016, 28 (14), 2795-800. 7. Tissa Sajoto, P. I. D., Arnold Tamayo, Muhammed Yousufuddin, Robert Bau, and Mark E. Thompson, Blue and Near-UV Phosphorescence from Iridium Complexes with Cyclometalated Pyrazolyl or N-Heterocyclic Carbene Ligands. Inorganic Chemistry 2005, 44 (22), 7992-8003. 8. Luo, J.; Xie, Z.; Lam, J. W. Y.; Cheng, L.; Tang, B. Z.; Chen, H.; Qiu, C.; Kwok, H. S.; Zhan, X.; Liu, Y.; Zhu, D., Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole. Chemical Communications 2001, (18), 1740-1741. 9. Jia Wang, Y. Z., Chuandong Dou, Hui Sun, Peng Xu, Kaiqi Ye, Jingying Zhang, Shimei Jiang, Fei Li, and Yue Wang, Alkyl and Dendron Substituted Quinacridones: Synthesis, Structures, and Luminescent Properties. J. Phys. Chem. B 207, 111, 5082-5089. 10. Bao Toan Nguyen, J. E. G., Chuanyong Ji, Pierre-Louis Brunner, My T. Nguyen, and X. X. Zhu, Enhancing the Photoluminescence Intensity of Conjugated Polycationic Polymers by Using Quantum Dots as Antiaggregation Reagents. Langmuir 2006, 22, 4799-4803

3. 毕业设计(论文)进程安排

11.01~12.20 师生见面,布置论文题目,了解基本情况,指导文献资料的查阅 12.20~12.31 初步了解课题,下达任务书 12.01~01.23 查阅文献,熟悉课题,完成文献综述、开题报告及文献翻译,准备实验所需药品和器材 03.02~05.31 进行毕业论文合成实验及相关表征测试 06.01~06.10 毕业论文撰写,修改 06.11~06.14 论文成稿,进行毕业论文答辩

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