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毕业论文网 > 任务书 > 化学化工与生命科学类 > 化学 > 正文

基于石墨烯/纳米金复合材料的酶生物传感器的构建与表征任务书

 2020-06-08 09:06  

1. 毕业设计(论文)的内容和要求

石墨烯是由碳原子堆积形成的平面晶体,其厚度仅是一个原子尺寸。

石墨烯特殊的结构(单原子厚度、 sp2 杂化的原子轨道、离域的大 π 键)决定了其在 光学、电学、热学、力学等方面拥有许多优异的性能。

石墨烯结构中含有大量的 π 键,层与层之间容易因为 π-π 堆积作用而相互堆叠在一 起,宏观上表现为石墨烯的团聚。

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2. 参考文献

[1] Ma J, Wang X, Liu Y, et al. Reduction of graphene oxide with l-lysine to prepare reduced graphene oxide stabilized with polysaccharide polyelectrolyte [J]. J Mater Chem A, 2013, 1(6):2192. [2] Liu H, Kuila T, Kim N H, et al. In situ synthesis of the reduced graphene oxide#8211; polyethyleneimine composite and its gas barrier properties [J]. J Mater Chem A, 2013, 1(11):3739. [3] Fernandez-Merino M J, Guardia L, Paredes J I, et al. Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions [J]. J Phys Chem C, 2010, 114(14):6426-6432. [4] M.D. Maksimovic, V.B. Miskovic-Stankovic, The corrosion behaviour of epoxy resin electrocoated steel, Corros. Sci. 33 (2) (1992) 271#8211;279. [5] S. Hiromoto, Self-healing property of hydroxyapatite and octacalcium phosphate coatings on pure magnesium and magnesium alloy, Corros. Sci. 100 (2015) 284#8211;294. [6] L. Ma, F. Chen, Z. Li, M. Gan, J. Yan, S. Wei, Y. Bai, J. Zeng, Preparation and anticorrosion property of poly(2,3-dimethylaniline) modified by nano-SiO2, Compos. Part B: Eng. 58 (2014) 54#8211;58. [7] J. Wang, R. Xu, Y. Zhang, Influence of SiO2 nano-particles on microstructures and properties of Ni#8211;W#8211;P/CeO2#8211;SiO2 composites prepared by pulse electrodeposition, Trans. Nonferrous Met. Soc. China 20 (5) (2010) 839#8211;843. [8] S. Sharifi Golru, M.M. Attar, B. Ramezanzadeh, Studying the influence of nano-Al2O3 particles on the corrosion performance and hydrolytic degradation resistance of an epoxy/polyamide coating on AA-1050, Prog. Org. Coat. 77 (9) (2014) 1391#8211;1399. [9] L. Liu, J. Xu, A study of the erosion-corrosion behavior of nano-Cr2O3 particles reinforced Ni-based composite alloying layer in aqueous slurry environment, Vacuum 85 (6) (2011) 687#8211;700. [10] Dongmei Cui, Li Mi, Xuan Xu, Jusheng Lu, Jing Qian, and Songqin Liu. Nanocomposites of graphene and cytochrome P450 2D6 isozyme for electrochemical-driven tramadol metabolism. Langmuir 2014, 30, 11833-11840. [11] Xuan Xu, Jiachao Yu, Jin Qian, Dongmei Cui, and Songqin Liu. Functionalization of nitrogen-doped carbon nanotubes by 1-pyrenebutyric acid and its application for biosensing. IEEE Sens J. 2014, 14(7), 2341-2346 [12] Henan Li, Yawen Mu, Junrong Yan, Dongmei Cui, Weijun Ou, Yakun Wan, and Songqin Liu. A label-free photoelectrochemical immunosensor for neutrophil gelatinase-associated lipocalin based on the novel use of nanobodies. Anal. Chem. 2015, 87, 2007-2015 [13] Jing Qian, Wei Zhu, Li Mi, Xuan Xu, Jiachao Yu, Dongmei Cui, Yanchun Xue, Songqin Liu. Nanohybrids of quantum dots and cytochrome P450 for light-driven drug metabolism. J. Electroanal. Chem. 2014, 733, 27-32. [14] L.B. Zhang, J.Q. Wang, H.G. Wang, Y. Xu, Z.F. Wang, Z.P. Li, Y.J. Mi, S.R. Yang, Preparation, mechanical and thermal properties of functionalized graphene/polyimide nanocomposites, Composites A 43 (2012) 1537#8211;1545. [15] I.H. Tseng, Y.F. Liao, J.C. Chiang, M.H. Chiang, Transparent polyimide/graphene oxide nanocomposite with improved moisture barrier property, Mater. Chem. Phys. 136 (2012) 247#8211;253. [16] L.B. Zhang, J.Q. Zhang, H.G. Wang, Y. Xu, Z.F. Wang, Z.P. Li, Y.J. Mi, S.R. Yang, Preparation, mechanical and thermal properties of functionalized graphene/polyimide nanocomposites, Compos. A #8211; Appl. Sci. Manuf. 43 (2012) 1537#8211;1545. [17] L. Yan, Y.B. Zheng, F. Zhao, S. Li, X. Gao, B. Xu, P.S. Weiss, Y. Zhao, Chemistry and physics of a single atomic layer: strategies and challenges for functionalization of graphene and graphene-based materials, Chem. Soc. Rev. 41 (2012) 97#8211;114. [18] Y. He, C. Tong, L. Geng, L. Liu, C. L#252;, Enhanced performance of the sulfonated polyimide proton exchange membranes by graphene oxide: size effect of graphene oxide, J. Membr. Sci. 458 (2014) 36#8211;46. [19] L.B. Zhang, J.Q. Wang, H.G. Wang, Y. Xu, Z.F. Wang, Z.P. Li, Y.J. Mi, S.R.Yang, Preparation, mechanical and thermal properties of functionalized graphene/polyimide nanocomposites, Composites A 43 (2012) 1537#8211;1545. [20] N.D. Luong, U. Hippi, J.T. Korhonen, A.J. Soininen, J. Ruokolainen, L.S. Johansson, J.D. Nam, L.H. Sinh, J. Sepp#228;l#228;, Enhanced mechanical and electrical properties of polyimide film by graphene sheets via in situ polymerization, Polymer 52 (2011) 5237#8211;5242.

3. 毕业设计(论文)进程安排

起讫日期 设计(论文)各阶段工作内容 备 注 2016.12.26-2017.3.1 查阅资料,完成开题报告和任务书 2017.3.2-2017.4.1 确定方案,学习实验过程和操作 2017.4.2-2017.5.13 独立实验,合成纳米材料并测试性能 2017.5.14-2017.6.12 数据整理,书写论文,制作PPT 2017.6.13- 修改论文并完成答辩

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