1. 毕业设计（论文）的内容和要求

氯化氢通过催化氧化可以制成氯气实现氯资源的循环利用，这对绿色化工生产和节能减排具有重大的价值。

为了推动该工艺的进一步工业化应用，必须能够开发出高效、廉价的催化剂。

ceo₂因一定的催化活性和稳定性而显示出良好的应用前景。

2. 参考文献

[1]Moser M, Mondelli C, Schmidt T, et al.Supported CeO₂ catalysts in technical form for sustainable chlorine production[J]. Applied Catalysis B,2013, 132-133: 123-131.[2]刘皓月, 费兆阳, 戴勇, 等 . 高比表面Ce_xTi_1-xO₂催化剂的结构表征及其HCl催化氧化性能[J]. 分子催化, 2014, 28(4): 329-335.[3]P#233;rez-Ram#237;rez J, Mondelli C, Schmidt T, et al. Sustainable chlorine recycling via catalysed HCl oxidation: from fundamentals to implementation[J]. Energy Environmental Science, 2011, 4(12): 4786.[4]Mortensen M K, Minet R G, Tsotsis T T, et al.A Two-stage Process for Catalytic Oxidation of Hydrogen Chloride to Chlorine[J]. Chemical Engineering Science, 1996, 51(10):2031-2039.[5]Kintrup J, Mleczko L, Schluter O, et al. Processes for the preparation of chlorine by gas phase oxidation[P]. US:20070292336, 2007-12-20.[6]Ricken M, N#246;lting J, Riess I. Specific heat and phase diagram of nonstoichiometric ceria (CeO_2-x)[J]. Journal of Solid State Chemistry,1984, 54(1): 89-99.[7]陈献. 氯化氢氧化CuCrK/Al₂O₃催化剂的研究[J]. 无机盐工业,2007, 39(4): 32~34.[8]Amrute A P, Mondelli C, Moser M, et al. Performance, structure, and mechanism of CeO 2 in HCl oxidation to Cl 2[J]. Journal of Catalysis, 2012, 286(4):287-297.[9]Madier Y, Descorme C, Le Govic A, et al.Oxygen Mobility in CeO₂ and Ce_x Zr_(1-x)O₂ Compounds: Study by CO Transient Oxidation and ¹⁸O/¹⁶O Isotopic Exchange[J]. The Journal of Physical Chemistry B,1999, 103(50): 10999-11006.[10]i R, Zhang YW, Li SJ, et al. Urea-Based Hydrothermally Derived Homogeneous Nanostructured Ce_1-xZr_xO₂(x= 0-0.8) Solid Solutions: A Strong Correlation between Oxygen Storage Capacity and Lattice Strain[J]. Journal of Physical Chemistry B,2004, 108(33): 12481-12488.[11]Trovarelli A, Zamar F, Llorca J, et al. Nanophase Fluorite-Structured CeO₂-ZrO₂ Catalysts Prepared by High-Energy Mechanical Milling[J]. Journal of Catalysis,1997, 169(2): 490-502.[12]谢兴星, 费兆阳, 戴勇, 等. 铈基复合氧化物的结构及其对HCl催化氧化性能的影响[J].分子催化, 2014(06): 28(6): 507-514.

3. 毕业设计（论文）进程安排

三月份上中旬翻译相关文献，撰写文献综述和开题报告；三月份下旬学习用浸渍法制备不同配比CeO₂/ZrO₂催化剂；四月份CeO₂/ZrO₂催化剂用于氯化氢氧化研究。

考察所制备催化剂的活性，优化反应条件；五月份上中旬对CeO₂/ZrO₂催化剂进行XRD、拉曼、TEM等表征分析，探索催化剂结构的和HCl催化氧化性能的构效关系，将表征的结果与催化剂的性能对应起来，对性能的优劣给出合理的解释，探索其催化反应机理；五月份下旬六月初准备答辩。