1. 毕业设计（论文）的内容和要求

1. 查阅相关文献了解目前在无溶剂合成方法与氮掺杂多孔碳材料的研究现状， 了解课题相关背景，已有成果以及存在的问题，对论文的研究方向有较深入的认识。

2. 增强分析问题解决问题的能力，培养独立思考及动手做实验的能力。

3. 了解实验仪器的具体使用方法和常规的表征方法。

2. 参考文献

1. James, S. L.; Adams, C. J.; Bolm, C.; Braga, D.; Collier, P.; Friscic, T.; Grepioni, F.; Harris, K. D.; Hyett, G.; Jones, W.; Krebs, A.; Mack, J.; Maini, L.; Orpen, A. G.; Parkin, I. P.; Shearouse, W. C.; Steed, J. W.; Waddell, D. C., Mechanochemistry: opportunities for new and cleaner synthesis. Chem Soc Rev 2012, 41 (1), 413-47. 2. Karak, S.; Kandambeth, S.; Biswal, B. P.; Sasmal, H. S.; Kumar, S.; Pachfule, P.; Banerjee, R., Constructing Ultraporous Covalent Organic Frameworks in Seconds via an Organic Terracotta Process. J Am Chem Soc 2017, 139 (5), 1856-1862. 3. Ren, L.; Wu, Q.; Yang, C.; Zhu, L.; Li, C.; Zhang, P.; Zhang, H.; Meng, X.; Xiao, F. S., Solvent-free synthesis of zeolites from solid raw materials. J Am Chem Soc 2012, 134 (37), 15173-6. 4. Ma, H.; Liu, B.; Li, B.; Zhang, L.; Li, Y. G.; Tan, H. Q.; Zang, H. Y.; Zhu, G., Cationic Covalent Organic Frameworks: A Simple Platform of Anionic Exchange for Porosity Tuning and Proton Conduction. J Am Chem Soc 2016, 138 (18), 5897-903. 5. Zhang, C.; Song, W.; Ma, Q.; Xie, L.; Zhang, X.; Guo, H., Enhancement of CO2 Capture on Biomass-Based Carbon from Black Locust by KOH Activation and Ammonia Modification. Energy Fuels 2016, 30 (5), 4181-4190. 6. Hirst, E. A.; Taylor, A.; Mokaya, R., A simple flash carbonization route for conversion of biomass to porous carbons with high CO2 storage capacity. Journal of Materials Chemistry A 2018, 6 (26), 12393-12403. 7. Mane, S.; Gao, Z.-Y.; Li, Y.-X.; Xue, D.-M.; Liu, X.-Q.; Sun, L.-B., Fabrication of microporous polymers for selective CO2 capture: the significant role of crosslinking and crosslinker length. Journal of Materials Chemistry A 2017, 5 (44), 23310-23318. 8. Qi, S.-C.; Liu, Y.; Peng, A.-Z.; Xue, D.-M.; Liu, X.; Liu, X.-Q.; Sun, L.-B., Fabrication of porous carbons from mesitylene for highly efficient CO2 capture: A rational choice improving the carbon loop. Chemical Engineering Journal 2019, 361, 945-952. 9. Goel, C.; Bhunia, H.; Bajpai, P. K., Resorcinol#8211;formaldehyde based nanostructured carbons for CO2 adsorption: kinetics, isotherm and thermodynamic studies. RSC Advances 2015, 5 (113), 93563-93578. 10. Mane, S.; Li, Y.-X.; Liu, X.-Q.; Yue, M. B.; Sun, L.-B., Development of Adsorbents for Selective Carbon Capture: Role of Homo- and Cross-Coupling in Conjugated Microporous Polymers and Their Carbonized Derivatives. ACS Sustainable Chemistry Engineering 2018, 6 (12), 17419-17426. 11. Geng, J.-C.; Xue, D.-M.; Liu, X.-Q.; Shi, Y.-Q.; Sun, L.-B., N-doped porous carbons for CO2capture: Rational choice of N-containing polymer with high phenyl density as precursor. AIChE Journal 2017, 63 (5), 1648-1658. 12. Kou, J.; Sun, L.-B., Nitrogen-Doped Porous Carbons Derived from Carbonization of a Nitrogen-Containing Polymer: Efficient Adsorbents for Selective CO2 Capture. Industrial Engineering Chemistry Research 2016, 55 (41), 10916-10925. 13. Sun, L.-B.; Kang, Y.-H.; Shi, Y.-Q.; Jiang, Y.; Liu, X.-Q., Highly Selective Capture of the Greenhouse Gas CO2 in Polymers. ACS Sustainable Chemistry Engineering 2015, 3 (12), 3077-3085. 14. Pietrzak, R., XPS study and physico-chemical properties of nitrogen-enriched microporous activated carbon from high volatile bituminous coal. Fuel 2009, 88 (10), 1871-1877. 15. Zhang, Y.; Liu, L.; Zhang, P.; Wang, J.; Xu, M.; Deng, Q.; Zeng, Z.; Deng, S., Ultra-high surface area and nitrogen-rich porous carbons prepared by a low-temperature activation method with superior gas selective adsorption and outstanding supercapacitance performance. Chemical Engineering Journal 2019, 355, 309-319. 16. Kim, J.; Abouelnasr, M.; Lin, L. C.; Smit, B., Large-scale screening of zeolite structures for CO2 membrane separations. J Am Chem Soc 2013, 135 (20), 7545-52. 17. Ma, X.; Li, Y.; Cao, M.; Hu, C., A novel activating strategy to achieve highly porous carbon monoliths for CO2 capture. J. Mater. Chem. A 2014, 2 (13), 4819-4826. 18. Zhang, P.; Zhong, Y.; Ding, J.; Wang, J.; Xu, M.; Deng, Q.; Zeng, Z.; Deng, S., A new choice of polymer precursor for solvent-free method: Preparation of N-enriched porous carbons for highly selective CO2 capture. Chemical Engineering Journal 2019, 355, 963-973. 19. Zhu, J.; Wu, L.; Bu, Z.; Jie, S.; Li, B.-G., Synthesis and CO2 Capture Behavior of Porous Cross-Linked Polymers Containing Pendant Triazole Groups. Industrial Engineering Chemistry Research 2017, 56 (36), 10155-10163. 20. Ma, X.; Zou, B.; Cao, M.; Chen, S.-L.; Hu, C., Nitrogen-doped porous carbon monolith as a highly efficient catalyst for CO2conversion. J. Mater. Chem. A 2014, 2 (43), 18360-18366. 21. Wang, J.; Heerwig, A.; Lohe, M. R.; Oschatz, M.; Borchardt, L.; Kaskel, S., Fungi-based porous carbons for CO2 adsorption and separation. Journal of Materials Chemistry 2012, 22 (28), 13911. 22. Su, F.; Poh, C. K.; Chen, J. S.; Xu, G.; Wang, D.; Li, Q.; Lin, J.; Lou, X. W., Nitrogen-containing microporous carbon nanospheres with improved capacitive properties. Energy Environ. Sci. 2011, 4 (3), 717-724. 23. Yang, F.; Wang, J.; Liu, L.; Zhang, P.; Yu, W.; Deng, Q.; Zeng, Z.; Deng, S., Synthesis of Porous Carbons with High N-Content from Shrimp Shells for Efficient CO2-Capture and Gas Separation. ACS Sustainable Chemistry Engineering 2018, 6 (11), 15550-15559.

3. 毕业设计（论文）进程安排

2019.2.26-2019.3.10 查阅收集文献资料，了解课题背景，完成开题报告的撰写,为实验准备工作 2019.3.11-2019.3.31 无溶剂条件下合成氮掺杂多孔碳材料 2019.4.1-2019.4.15 对合成的样品进行相应的表征测试，并且撰写中期自查表 2019.4.16-2019.4.30 探索吸附剂的吸附性能，同时撰写毕业论文。