1. 毕业设计（论文）的内容和要求

文献综述能够比较详尽地总结合成气制异丁醇催化剂的研究进展，包括异丁醇的用途及生产现状，合成气制醇的催化剂类别及各自特点，以及不同组成，不同形貌纳米金属催化剂对合成气制异丁醇的性能影响。

详细列出实验所用试剂和分析仪器，实验方法具有一定独创性，杜绝简单重复前人的工作，能够独立提出本课题实验设计方案。

并制备出一至两种工艺简单且性能有特点的合成气转化催化剂，同时对所制备的催化剂进行sem、xrd、h2-tpr等表征，并在固定床反应器上进行性能评价。

2. 参考文献

[1] Gao X, Wu Y, Tao Z, et al. Binary ZnO/Zn#8211;Cr nanospinel catalysts prepared by a hydrothermal method for isobutanol synthesis from syngas[J]. Catalysis Science Technology, 2018, 8(11). [2] Tian S, Li T, Wu Y, et al. The role of different state ZnO over non-stoichiometric Zn#8211;Cr spinel catalysts for isobutanol synthesis from syngas[J]. Applied Catalysis A General, 2017, 536:57-66. [3] Gao X, Wu Y, Yang G, et al. Insight into the role of hydroxyl groups on the ZnCr catalyst for isobutanol synthesis from syngas[J]. Applied Catalysis A General, 2017, 547:S0926860X17304027. [4] Cheng S Y, Kou J W, Gao Z H, et al. Preparation of complexant-modified Cu/ZnO/Al2O3 catalysts via hydrotalcite-like precursors and its highly efficient application in direct synthesis of isobutanol and ethanol from syngas[J]. Applied Catalysis A General, 2018, 556:113-120. [5] Cheng S Y, Gao Z H, Kou J W, et al. Direct Synthesis of Isobutanol from Syngas over Nanosized Cu/ZnO/Al2O3 Catalysts Derived from Hydrotalcite-like Materials Supported on Carbon Fibers[J]. Energy Fuels, 2017, 31(8):8572-8579. [6] Tian S, Wu Y, Li K, et al. Isobutanol synthesis from syngas over Zn‐Cr catalyst: effect of Zn/Cr element ratio[J]. Energy Technology, 2018. [7] Daiping H E, Ding Y, Yin H, et al. Effect of Alkali Promoters on Catalytic Performance of MnOx/ZrO2 for Synthesis of Methanol and Isobutanol from Syngas[J]. Chinese Journal of Catalysis, 2003, 24(2):111-114. [8] Wu Y , Xie H , Tian S , et al. Isobutanol synthesis from syngas over K#8211;Cu/ZrO2#8211;La2O3(x) catalysts: Effect of La-loading[J]. Journal of Molecular Catalysis A: Chemical, 2015, 396:254-260. [9] Tao J, Niu Y, Bing Z. Synthesis of higher alcohols from syngas over Zn#8211;Cr#8211;K catalyst in supercritical fluids[J]. Fuel Processing Technology, 2001, 73(3):175-183. [10] Tian S , Wang S , Wu Y , et al. Cation distribution in Zn#8211;Cr spinel structure and its effects on synthesis of isobutanol from syngas: Structure#8211;activity relationship[J]. Journal of Molecular Catalysis A: Chemical, 2015, 404-405:139-147. [11] 武应全, 王思晨, 解红娟, et al. Cu对K-LaZrO_2异丁醇合成催化剂的影响[J]. 物理化学学报, 2015(1). [12] Ying-Quan W U, Xie H J, Kou Y L, et al. Effect of calcination temperature on performance of K-Cu/Zn/La/ZrO2 for isobutanol synthesis[J]. Journal of Fuel Chemistry Technology, 2013, 41(7):868-874. [13] Sun Y, Sun Q W, Jiang F K, et al. Effects of calcination and reduction temperatures on the performance of Co-Pt-ZrO2/Y-Al2O3 catalysts for Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry Technology, 2012, 40(1):54-58. [14] Zhao N, Yang C, Wei W, et al. Effect of calcination temperature on Cu/Mn/Ni/ZrO2 catalyst for synthesis of higher alcohols[J]. Chinese Journal of Catalysis, 2002, 23(6):463-9.

3. 毕业设计（论文）进程安排

2017, 2, 25 #8210; 2017, 3, 10：查阅翻译文献，深入理解研究异丁醇用途，生产工艺改进的意义，常见催化剂的分类、特点及制备方法。

撰写本研究方向的文献综述。

2017, 3, 11 #8210; 2017, 5, 31：熟悉并掌握实验仪器设备的使用与操作，掌握共沉淀法制备纳米催化剂的实验方法、溶液配制方法，进行合成实验与产物的分析测试，优化实验条件(元素选取、原料配比等)，选用不同材料合成金属纳米颗粒尺寸均匀、分散度高、还原度好的多元金属纳米催化剂，并在固定床反应器中初步研究催化剂催化合成气制异丁醇的性能。