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毕业论文网 > 任务书 > 化学化工与生命科学类 > 化学工程与工艺 > 正文

电吸附与膜技术的脱盐过程研究任务书

 2020-04-24 11:04  

1. 毕业设计(论文)的内容和要求

本课题要求在查阅文献和具体实验的基础上,了解并掌握反渗透膜设备即电吸附设备的操作方法,掌握反渗透膜的表征手段和方法,熟悉反渗透膜和电吸附的基本性能及分离机理,并了解膜技术及电吸附技术的应用领域及研究状况。

了解并掌握不同操作条件对膜过程及电吸附过程脱盐效果的影响,优化操作条件以控制膜污染和电极污染,从而达到在过滤过程中获得长期稳定膜通量及高脱盐率的目的。

2. 参考文献

[1] Chen D, Hou J, Yao L, et al. Ferrite Materials Prepared from Two Industrial Wastes: Electroplating Sludge and Spent Pickle Liquor[J]. Separation and Purification Technology, 2010, 75(2): 210-217. [2] 解彦刚, 蔡凤, 李斯恩, 等. 电极箔腐蚀废酸的资源化试验研究[J].中国给水排水, 2014, 30 (21): 118-120. [3] 高廷耀, 顾国维. 水污染控制工程[M]. 高等教育出版社. 1999. [4] 杨智宽, 韦进宝. 污染控制化学[M]. 武汉大学出版社, 1997. [5] Regel-Rosocka M. A Review On Methods of Regeneration of Spent Pickling Solutions from Steel Processing[J]. Journal of Hazardous Materials, 2010, 177(1-3): 57-69. [6] 张孟民, 石洁. 钢材盐酸酸洗废液资源化处理的研究[J]. 环境科学与技术, 2006, 29(7): 66-67. [7] Gal#225;n B, Castantilde;eda D, Ortiz I. Removal and Recovery of Cr(VI) from Polluted Ground Waters: A Comparative Study of Ion-Exchange Technologies[J]. Water Research, 2005, 39(18): 4317-4324. [8] 贾美欣. 醋酸稀溶液的萃取动力学研究[D]. 山东科技大学, 2008. [9] Albin Pintar, Jurka Batista, Janez Levec, Integrated ion exchange/catalytic process for efficient removal of nitrates from drinking water[J]. Chemical Engineering Science ,2001,56: 1551-155. [10] 杨春锁, 方循华. 梅山冷轧酸洗废水实行蒸馏处理[J]. 冶金环境保护, 2001, (2): 43. [11] 黄万抚, 何善媛. 钢铁酸洗废水处理与回收利用[J]. 冶金丛刊, 2005, 6(5): 33-36. [12] 隋洁, 鲁毅强, 石健. 钢铁酸洗废液的资源化处理技术[J]. 工业用水与废水, 2003, 34(3): 36-39. [13] Tongwen X, Weihua Y. Industrial Recovery of Mixed Acid (HF HNO3) from the Titanium Spent Leaching Solutions by Diffusion Dialysis with a New Series of Anion Exchange Membranes[J]. Journal of Membrane Science, 2003, 220(1-2): 89-95. [14] Wei C, Li X, Deng Z, et al. Recovery of H2SO4 from an Acid Leach Solution by Diffusion Dialysis[J]. Journal of Hazardous Materials, 2010, 176(1-3): 226-230. [15] Luo J Y, Wu C M, Xu T W, et al. Diffusion dialysis-concept, principle and applications[J]. Journal of Membrane Science, 2011, 366: 1-16. [16] Xu J, Lu S G, Fu D. Recovery of hydrochloric acid from the waste acid solution by diffusion dialysis[J]. Journal of Hazardous Materials, 2009, 165, 832-837. [17] Mao F, Zhang G, Tong J, et al. Anion Exchange Membranes Used in Diffusion Dialysis for Acid Recovery from Erosive and Organic Solutions[J]. Separation and Purification Technology, 2014, 122: 376-383 [18] 刘羊九, 王云山, 韩吉田, 等. 膜蒸馏技术研究及应用进展[J]. 化工进展, 2018, 37(10): 3726-3736. [19] Kesieme U K, Milne N, Cheng C Y, et al. Recovery of Water and Acid from Leach Solutions Using Direct Contact Membrane Distillation[J]. Water Science and Technology, 2014, 69(4): 868. [20] 刘荣玲. 多效膜蒸馏过程用于深度浓缩稀盐酸水溶液的研究[D]. 天津大学, 2012. [21] GONZAacute;LEZ D, AMIGO J, SUAacute;REZ F. Membrane distillation: perspectives for sustainable and improved desalination[J]. Renewable and Sustainable Energy Reviews, 2017, 80: 238-259. [22] 张维润. 电渗析工程学[M]. 北京: 科学出版社, 2004. [23] Negro C, Blanco M A, Lopez-Mateos F, et al. Free Acids and Chemicals Recovery from Stainless Steel Pickling Baths[J]. Separation Science and Technology, 2001, 36(7): 1543-1556. [24] Bes-Pi#225; A, Cuartas-Uribe B, Mendoza-Roca J A, et al. Pickling Wastewater Reclamation by Means of Nanofiltration[J]. Desalination, 2008, 221(1-3): 225-233. [25] Lee P, Li C, Chen J, et al. Dissolution of D2EHPA in Liquid#8211;Liquid Extraction Process: Implication On Metal Removal and Organic Content of the Treated Water[J]. Water Research, 2011, 45(18): 5953-5958. [26] Lohithakshan K V, Patil P, Aggarwal S K. Solvent Extraction Studies of plutonium(IV) and americium(III) in Room Temperature Ionic Liquid (RTIL) by Di-2-Ethyl Hexyl Phosphoric Acid (HDEHP) as Extractant[J]. Journal of Radioanalytical and Nuclear Chemistry, 2014, 301(1): 153-157. [27] Shin C, Kim J, Kim J, et al. Recovery of Nitric Acid from Waste Etching Solution Using Solvent Extraction[J]. Journal of Hazardous Materials, 2009, 163(2-3): 729-734. [28] Kesieme U K, Aral H, Duke M, et al. Recovery of Sulphuric Acid from Waste and Process Solutions Using Solvent Extraction[J]. Hydrometallurgy, 2013, 138: 14-20. [29] Fischer L, Falta T, Koellensperger G, et al. Ionic Liquids for Extraction of Metals and Metal Containing Compounds from Communal and Industrial Waste Water[J]. Water Research, 2011, 45(15): 4601-4614.

3. 毕业设计(论文)进程安排

1、3月1号至3月10号#8212;#8212;准备阶段 对相关文献进行翻译,并撰写实验计划和开题报告。

2、3月10号4月中旬#8212;#8212;实验阶段 对膜的基本性能进行表征,并对实验模拟溶液进行膜过程实验;调节不同操作条件,考察电吸附过程的脱盐效果;对膜过程及电吸附过程进行耦合,优化操作条件。

3、4月中旬到5月中旬#8212;#8212;总结阶段 通过对实验数据分析计算,掌握反渗透膜基本性能表征方法,考察并了解反渗透膜及电吸附的基本性能及分离机理。

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