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毕业论文网 > 任务书 > 化学化工与生命科学类 > 化学工程与工艺 > 正文

磷钨酸固载在氨基化金属有机骨架的制备及其催化性能研究任务书

 2020-06-26 07:06  

1. 毕业设计(论文)的内容和要求

1、培养学生巩固和扩展并综合运用所学的基础理论和专业知识,培养学生运用所学知识独立分析、解决实际问题能力; 2、培养学生初步的科研能力、创新意识和创新能力; 3、培养学生自己动手做实验的能力,研究反应条件,分析处理实验结果数据的能力; 4、培养学生正确的研究思想、理论联系实际的工作作风和严肃的科学态度; 5、培养学生与他人协作的能力和刻苦钻研、勇于创新的精神; 6、培养学生进行方案设计、文献资料查阅整理、理论计算、外文资料的阅读和翻译、文字表达等方面的能力和技巧以及提出论点、综合论证、总结写作等基本技能。

2. 参考文献

1. Wee L H, Janssens N, Bajpe S R, et al. Heteropolyacid encapsulated in Cu 3 (BTC) 2 nanocrystals: An effective esterification catalyst[J]. Catalysis today, 2011, 171(1): 275-280. 2. Dou J, Zeng H C. Targeted synthesis of silicomolybdic acid (keggin acid) inside mesoporous silica hollow spheres for Friedel#8211;Crafts alkylation[J]. Journal of the American Chemical Society, 2012, 134(39): 16235-16246. 3. Sulikowski B, Haber J, Kubacka A, et al. Novel ”ship-in-the-bottle” type catalyst: evidence for encapsulation of 12-tungstophosphoric acid in the supercage of synthetic faujasite[J]. Catalysis letters, 1996, 39(1-2): 27-31. 4. Mukai S R, Ogino I, Lin L, et al. A stable" Ship in the Bottle" type 12-Molybdophosphoric acid encaged Y-type zeolite catalyst for liquid phase reactions[J]. Reaction Kinetics and Catalysis Letters, 2000, 69(2): 253-258. 5. F#233;rey G, Mellot-Draznieks C, Serre C, et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area[J]. Science, 2005, 309(5743): 2040-2042. 6. Hong D Y, Hwang Y K, Serre C, et al. Porous Chromium Terephthalate MIL‐101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis[J]. Advanced Functional Materials, 2009, 19(10): 1537-1552. 7. Yang J, Zhao Q, Li J, et al. Synthesis of metal#8211;organic framework MIL-101 in TMAOH-Cr (NO3)3-H2BDC-H2O and its hydrogen-storage behavior[J]. Microporous and Mesoporous Materials, 2010, 130(1): 174-179. 8. Luo X P, Fu S Y, Du Y M, et al. Adsorption of methylene blue and malachite green from aqueous solution by sulfonic acid group modified MIL-101[J]. Microporous and Mesoporous Materials, 2017, 237: 268-274. 9. Barcia P S, Zapata F, Silva J A C, et al. Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework[J]. The Journal of Physical Chemistry B, 2007, 111(22): 6101-6103. 10. Luo X P, Fu S Y, Du Y M, et al. Adsorption of methylene blue and malachite green from aqueous solution by sulfonic acid group modified MIL-101[J]. Microporous and Mesoporous Materials, 2017, 237: 268-274. 11. Saikia M, Bhuyan D, Saikia L. Facile synthesis of Fe 3 O 4 nanoparticles on metal organic framework MIL-101 (Cr): characterization and catalytic activity[J]. New Journal of Chemistry, 2015, 39(1): 64-67. 12. Juan-Alca#241;iz J, Ramos-Fernandez E V, Lafont U, et al. Building MOF bottles around phosphotungstic acid ships: One-pot synthesis of bi-functional polyoxometalate-MIL-101 catalysts[J]. Journal of Catalysis, 2010, 269(1): 229-241. 13. Bromberg L, Diao Y, Wu H, et al. Chromium (III) terephthalate metal organic framework (MIL-101): HF-free synthesis, structure, polyoxometalate composites, and catalytic properties[J]. Chemistry of Materials, 2012, 24(9): 1664-1675.

3. 毕业设计(论文)进程安排

1.2018年2月-3月:查找相关文献,熟悉课题研究背景,并完成一篇外文翻译 2.2018年3月-4月:完成开题报告,制定实验计划 3.2018年4月-5月:进行实验,对产品进行表征,得出数据 4.2018年5月-6月:完成论文的撰写

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