1. 毕业设计（论文）的内容和要求

设计一种新型离子液体。

合成方法：苯酚咪唑和碘代正丁烷合成一种新颖的离子液体，将此催化剂应用于CO2环加成反应中，并设计对比催化剂，对机理有深入的认识。

2. 参考文献

[1] aY. Xie, T. T. Wang, X. H. Liu, K. Zou, W. Q. Deng, Nat Commun 2013, 4, 1960; bY. Zhao, B. Yu, Z. Yang, H. Zhang, L. Hao, X. Gao, Z. Liu, Angewandte Chemie International Edition 2014, 53, 5922-5925. [2] M. Cokoja, M. E. Wilhelm, M. H. Anthofer, W. A. Herrmann, F. E. Kuhn, ChemSusChem 2015, 8, 2436-2454. [3] F. D. Bobbink, P. J. Dyson, Journal of Catalysis 2016, 343, 52-61. [4] Z. Guo, Q. Jiang, Y. Shi, J. Li, X. Yang, W. Hou, Y. Zhou, J. Wang, ACS Catalysis 2017, 7, 6770-6780. [5] aJ. A. Castro-Osma, K. J. Lamb, M. North, ACS Catalysis 2016, 6, 5012-5025; bF. Zhou, S.-L. Xie, X.-T. Gao, R. Zhang, C.-H. Wang, G.-Q. Yin, J. Zhou, Green Chemistry 2017, 19, 3908-3915; cJ. A. Castro-Osma, M. North, X. Wu, Chemistry 2016, 22, 2100-2107. [6] aM. H. Beyzavi, R. C. Klet, S. Tussupbayev, J. Borycz, N. A. Vermeulen, C. J. Cramer, J. F. Stoddart, J. T. Hupp, O. K. Farha, Journal of the American Chemical Society 2014, 136, 15861-15864; bW.-Y. Gao, Y. Chen, Y. Niu, K. Williams, L. Cash, P. J. Perez, L. Wojtas, J. Cai, Y.-S. Chen, S. Ma, Angewandte Chemie International Edition 2014, 53, 2615-2619; cP.-Z. Li, X.-J. Wang, J. Liu, J. S. Lim, R. Zou, Y. Zhao, Journal of the American Chemical Society 2016, 138, 2142-2145. [7] aG. Ji, Z. Yang, H. Zhang, Y. Zhao, B. Yu, Z. Ma, Z. Liu, Angew Chem Int Ed Engl 2016, 55, 9685-9689; bZ. Dai, Q. Sun, X. Liu, C. Bian, Q. Wu, S. Pan, L. Wang, X. Meng, F. Deng, F.-S. Xiao, Journal of Catalysis 2016, 338, 202-209. [8] C. J. Whiteoak, A. Nova, F. Maseras, A. W. Kleij, ChemSusChem 2012, 5, 2032-2038. [9] J. Wang, Y. Zhang, ACS Catalysis 2016, 6, 4871-4876. [10] aV. B. Saptal, B. M. Bhanage, Chemsuschem 2017, 10, 1145-1151; bS. Liu, N. Suematsu, K. Maruoka, S. Shirakawa, Green Chemistry 2016, 18, 4611-4615. [11] aH. Braunschweig, A. Damme, R. D. Dewhurst, A. Vargas, Nat Chem 2013, 5, 115-121; bN. Holzmann, D. Dange, C. Jones, G. Frenking, Angew Chem Int Ed Engl 2013, 52, 3004-3008.

3. 毕业设计（论文）进程安排

3月上旬，查阅文献，掌握相关的背景知识。

3月下旬-4月下旬，合成离子液体单体。

5月上旬-5月中旬，此催化剂应用于二氧化碳转化。