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毕业论文网 > 任务书 > 化学化工与生命科学类 > 化学工程与工艺 > 正文

改性的氧化石墨烯吸附剂对Ag 的吸附研究任务书

 2020-06-11 10:06  

1. 毕业设计(论文)的内容和要求

查阅相关文献与专业书籍了解目前处理含银废水的研究现状,了解氧化石墨烯的制备方法,了解吸附研究基础知识。

了解现有研究成果以及存在的问题,对论文的研究方向有较深入的认识。

培养学生独立思考及动手做实验的能力,养成良好的科研习惯。

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2. 参考文献

[1]V.I.E. Ajiwe *, I.E. Anyadiegwu. Recovery of silver from industrial wastes,cassava solution effects[J]. Separation and Purification Technology 18 (2000) 89#8211;92 [2]刘强.贵金属的生物吸附[J].信息纵横,2012,2. [3]陈理想,吴平霄,杨林,祝雅杰. 巯基乙胺改性蛭石对水体中Ag_I_的吸附性能研究[J].中国环境科学,2015,35(4). [4]武文琴.氧化石墨烯及其复合材料对重金属铜的吸附性能研究[D].湖南大学,2013. [5]郝梦秋.氧化石墨烯_铁氧化物复合吸附剂的制备及性能研究[D].中南大学.2014. [6]肖玲,陈艺羡. 氧化石墨_壳聚糖磁性复合吸附剂对活性艳红吸附性能研究[Z].1671-8844(2012)06-0860-05.2012-08-06. [7] Lin Wanga.Recovery of silver (I) using a thiourea-modified chitosan resin[J].Journal of Hazardous Materials.2010,180. [8] Yulia S. Petrovaa.Selective adsorption of silver(I) ions over copper(II) ions on asulfoethyl derivative of chitosan[J].Journal of Hazardous Materials.2015,299. [9]肖蓝.石墨烯及其复合材料在水处理中的应用[J].化学进展.2013,25. [10]胡忠良.石墨烯材料在水处理方面的研究进展[J].功能材料.2016,增刊(I). [11]邓会.石墨烯材料在水处理中的应用传质机制与吸附特性[J].科学通报.2015,60. [12]Hu-Chun Tao.Recovery of silver from silver(I)-containing solutions in bioelectrochemical reactors[J]. Bioresource Technology.2012,111. [13]杨熙.氧化石墨烯和石墨烯纳米材料制备及其重金属吸附性能研究[D].华中师范大学,2012. [14]杨胜韬.石墨烯吸附材料的制备与应用研究进展[J].西南民族大学学报.2014,40. [15]Ahmed M. Donia.Recovery of gold(III) and silver(I) on a chemically[J].ScienceDirect.2007,87. [16] A. Webster, M.D. Halling, D.M. Grant, Metal complexation of chitosan and its glutaraldehyde cross-linked derivative, Carbohydr. Res. 342 (2007) 1189#8211;1201, http://dx.doi.org/10.1016/j.carres.2007.03.008 [17] X. Wang, Y. Du, L. Fan, H. Liu, Y. Hu, Chitosan-metal complexes as antimicrobial agent: synthesis, characterization and structure-activity study, Polym. Bull. 55 (2005) 105#8211;113, http://dx.doi.org/10.1007/s00289-005-0414-1 [18] Y. Baba, H. Hirakawa, K. Yoshiziuka, K. Inoue, Y. Kawano, Adsorption equilibria of silver(I) and copper(II) N-(2-hydroxylbenzyl) chitosan derivative, Anal. Sci. 10 (1994) 601#8211;605, http://dx.doi.org/10.2116/analsci.10.601 [19] S.Yu Hirakawa, Yu.A. Azarova, E.G. Matochkina, M.I. Kodess, Yu.G. Yatluk, A.V. Pestov, N-(2-(2-pyridyl) ethyl) chitosan: synthesis, characterization and sorption properties, Carbohydr. Polym. 87 (2012) 869#8211;875, http://dx.doi.org/ 10.1016/j.carbpol.2011.08.081 [20] A.V. Pestov, S.Yu. Bratskaya, Yu.A. Azarova, M.I. Kodess, Yu.G. Yatluk, N-2-(2-pyridyl) ethyl chitosan: synthesis in gel and sorption properties, Russ. J. Appl. Chem. 84 (2011) 713#8211;718, http://dx.doi.org/10.1134/ S1070427211040276 [21] C.A. Rodrigues, M.C.M. Laranjeira, V.T. Favere, E. Stadler, Interaction Cu(II) on N-(2-pyridylmethyl) and N-(4-pyridylmethyl) chitosan, Polymer 39 (1998) 5121#8211;5126, http://dx.doi.org/10.1016/S0032-3861(97)10190-2 [22] K.Z. Elwakeel, G.O. El-Sayed, R.S. Darweesh, Fast and selective removal of silver(I) from aqueous media by modified chitosan resins, Int. J. Miner. Process. 120 (2013) 26#8211;34, http://dx.doi.org/10.1016/j.minpro.2013.02.007 [23] A.M. Donia, A.A. Atia, K.Z. Elwakeel, Recovery of gold(III) and silver(I) on a chemically modified chitosan with magnetic properties, Hydrometallurgy 87 (2007) 197#8211;206, http://dx.doi.org/10.1016/j.hydromet.2007.03.007 [24] L. Fan, C. Luo, Z. Lv, F. Lu, H. Qiu, Removal of Ag from water environment using a novel magnetic thiourea-chitosan imprinted Ag , J. Hazard. Mater. 194 (2011) 193#8211;201, http://dx.doi.org/10.1016/j.jhazmat.2011.07.080 [25] L. Wang, R. Xing, S. Liu, H. Yu, Y. Qin, K. Li, J. Feng, R. Li, P. Li, Recovery of silver(I) using a thiourea-modified chitosan resin, J. Hazard. Mater. 180 (2010) 57#8211;582, http://dx.doi.org/10.1016/j.jhazmat.2010.04.072 [26] S. Sun, A. Wang, Adsorption kinetics of Cu(II) ions using N,O-carboxymethyl-chitosan, J. Hazard. Mater. 131 (2006) 103#8211;111, http:// dx.doi.org/10.1016/j.jhazmat.2005.09.012 [27] S. Sun, A. Wang, Adsorption properties of carboxymethyl-chitosan and cross-linked carboxymethyl-chitosan resin with Cu(II) as template, Sep. Purif. 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3. 毕业设计(论文)进程安排

1、1月1号至1月10号#8212;#8212;准备阶段 对相关文献进行翻译,并撰写实验计划和开题报告。

2、1月15号-3月-----阅读文献阶段 大量阅读文献并进行实验方案的修改,完善实验步骤 3、3月10号4月中旬#8212;#8212;实验阶段 制备氧化石墨烯和壳聚糖复合材料,对复合产物的基本性能进行表征,进行吸附实验。

4、4月中旬到5月中旬#8212;#8212;总结阶段 通过对实验数据分析计算,掌握吸附动力学,热力学,等温曲线研究。

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