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毕业论文网 > 任务书 > 化学化工与生命科学类 > 化学工程与工艺 > 正文

氟掺杂量对钙钛矿膜材料性能的影响任务书

 2020-06-09 10:06  

1. 毕业设计(论文)的内容和要求

本项目拟通过氟离子掺杂调整钙钛矿结构参数,系统研究氟的掺杂量对材料氧渗透行为及稳定性的影响及作用机理,提高材料在低温的氧离子传输速率,从而获得高性能的氧分离膜。

具体研究内容如下: 氟的掺杂量对钙钛矿材料氧渗透行为的影响 主要研究氟的掺杂量对钙钛矿型混合导体膜材料的结构组成的影响;氟的掺杂量对钙钛矿型混合导体膜制备过程的影响。

氟的掺杂量对钙钛矿型混合导体膜材料的氧渗透性能以及氧传输机理的影响。

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2. 参考文献

[1] R. Bredesen, K. Jordal, A. Bolland, High-temperature membranes in power generation with CO2 capture. Chem. Eng. Process., 43 (2004) 1129#8722;1158. [2] S. Holloway, Underground sequestration of carbon dioxide #8211; a viable greenhouse gas mitigation option. Energy, 30 (2005) 2318#8722;2333. [3] 金万勤,徐南平,混合导体氧渗透膜设计、制备与应用, 2013,北京. [4] Y. Lin, W. Wang and J. Han, AIChE J. 40 (1994) 786. [5] J. Sunarso, S. Baumann, J. M. Serra, W. A. Meulenberg, S. Liu, Y. S. Lin and J. C. D. da Costa, J. Membr. Sci. 2008, 320, 13. [6] R. van Doorn, H. Kruidhof, A. Winnubst, A. Burggraaf, Preparation of La0.3Sr0.7CoO3-δ perovskite by thermal decomposition of metal-EDTA complexes J. Mater. Chem., 8 (1998) 2109-2112 [7] H. Bouwmeester, A. Burggraaf, Fundamentals of inorganic membrane science and technology, Amsterdam: Elsevier, (1996) 435-515. [8] J. Sunarso, S. Baumann, J. Serra, et al, Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation, J. Membr. Sci., 320 (2008) 13-41. [9] Z. Wu, W. Zhou, W. Jin, et al, Effect of PH on synthesis and properties of perovskite oxide via a citrate process, AIChE J., 52 (2006) 769-776. [10] P. Hoon, Kim, J. Pyo, Kwon, H. Taek, Oxygen permeability, electrical property and stability of La(0.8)Sr(0.2)Co(0.2)Fe(0.8)O(3-delta) membrane, Desalination, 233 (2008) 73-81. [11] Z. Shao, H. Dong, G. Xiong, et al. Performance of a mixed-conducting ceramic membrane reactor with high oxygen permeability for methane conversion. J. Membr. Sci., 183 (2001) 181-192. [12] Z. Shao, W. Yang, Y. Cong, et al, Investigation of the permeation behavior and stability of a Ba0.5Sr0.5Co0.8Fe0.2O3-delta oxygen membrane, J. Membr. Sci., 172 (2000) 177-188. [13] P. Zeng, Z. Chen, W. Zhou, et al, Re-evaluation of Ba0.5Sr0.5Co0.8Fe0.2O3-delta perovskite as oxygen semi-permeable membrane, J. Membr. Sci., 291 (2007) 148-156. [14] X. Dong, W. Jin, N. Xu, Reduction-Tolerant Oxygen-Permeable Perovskite-Type Oxide Sr0.7Ba0.3Fe0.9Mo0.1O3-δ, Chem. Mater. 22 (2010) 3610#8211;3618. [15] J. Zhu, S. Guo, Z. Chu, W. Jin, CO2-tolerant oxygen-permeable perovskite-type membranes with high permeability, J. Mater. Chem. A, 3 (2015) 22564-22573. [16] K. Tetsuya, N. Subaru, W. Ken, et al, High Oxygen Permeation in Ba0.95La0.05FeO3-delta Membranes with Surface Modification, ACS Appl. Mater. Inter., 2 (2010)2849-2853. [17] P. Kaveh, F. Liang, Ravkina, Olga, et al, High-Flux Oxygen Transporting Membrane Pr0.6Sr0.4Co0.5Fe0.5O3-delta: CO2 Stability and Microstructure, ACS Appl. Mater. Inter., 6 (2014) 10274-10282. [18] J. Zhu, G. Liu, Z. Liu, Z. Chu, W. Jin, N. Xu, Unprecedented Perovskite Oxyfluoride Membranes with High-Efficiency Oxygen Ion Transport Paths for Low-Temperature Oxygen Permeation, Adv. Mater., 28 (2016) 3511-3515.

3. 毕业设计(论文)进程安排

2016. 07-2017.06: 阅读大量文献,并结合实验,筛选合适的钙钛矿母体氧化物,用于后续的氟掺杂。

探索氟掺杂钙钛矿材料的制备方法,制备条件,找到一种简单易行的制备方法,并制备出不同氟掺杂量的钙钛矿型混合导体材料。

探索用所获得的材料制备致密的片式膜。

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