1. 毕业设计（论文）的内容和要求

设计合成高孔性配位聚合物，并研究它们在能源气体相关存储和分离的研究。

要求能够实现一个新化合物的制备和完整表征。

掌握各种仪器的使用。

2. 参考文献

1. Horcajada P, et al. Porous metal-organic-framework nanoscale carriers as a potential platform for drug delivery and imaging. Nat Mater 9, 172-178 (2010). 2. Ferey G, et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 309, 2040-2042 (2005). 3. Duan J, Jin W, Kitagawa S. Water-resistant porous coordination polymers for gas separation. Coord Chem Rev 332, 48-74 (2017). 4. Duan JG, Yang Z, Bai JF, Zheng BS, Li YZ, Li SH. Highly selective CO2 capture of an agw-type metal-organic framework with inserted amides: experimental and theoretical studies. Chem Commun 48, 3058-3060 (2012). 5. Luebke R, et al. Versatile rare earth hexanuclear clusters for the design and synthesis of highly-connected ftw-MOFs. Chem Sci 6, 4095-4102 (2015). 6. Nugent P, et al. Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation. Nature 495, 80-84 (2013).

3. 毕业设计（论文）进程安排

3月 配体合成， 4月 晶体合成，晶体表征， 5月 性能测试及性能表征， 6月 总结和组织论文