1. 毕业设计（论文）的内容和要求

近年来，一种新型的碳原子材料#8212;#8212;石墨烯（graphene）材料，得到研究者的广泛关注。

2004 年英国科学家geim及novoselov 等人利用胶带剥离石墨的方法首次制备出稳定的高质量的单层石墨烯，并获得了2010 年的诺贝尔物理学奖。

由于石墨烯突出的物理化学性质，近两年石墨烯材料在分离膜上的应用也得到了广泛的关注，并取得了可观的结果。

2. 参考文献

[1] 陈勇, 王从厚, 吴鸣. 气体膜分离技术与应用[M]. 化学工业出版社. 2004. [2] Peng Yuan, Li Yanshuo,Ban Yujie, et al. Metal-organic framework nanosheets as building blocks for molecular sieving membranes. SCIENCE. 2014. 346(6215): 1356-1359. [3] Qiao Zhen-An, Chai Song-Hai,Nelson Kimberly, et al. Polymeric molecular sieve membranes via in situ cross-linking of non-porous polymer membrane templates. NATURE COMMUNICATIONS. 2014. 5(3705). [4] Kim Hyo Won, Yoon Hee Wook,Yoo Byung Min, et al. High-performance CO2-philic graphene oxide membranes under wet-conditions. CHEMICAL COMMUNICATIONS. 2014. 50(88): 13563-13566. [5] Ohba Tomonori. The Thinnest Molecular Separation Sheet by Graphene Gates of Single-Walled Carbon Nanohorns. ACS NANO. 2014. 8(11): 11313-11319. [6] Shen Jie, Liu Gongping,Huang Kang, et al. Membranes with Fast and Selective Gas-Transport Channels of Laminar Graphene Oxide for Efficient CO2 Capture. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2015. 54(2): 578-582. [7] Li Xueqin, Cheng Youdong,Zhang Haiyang, et al. Efficient CO2 Capture by Functionalized Graphene Oxide Nanosheets as Fillers To Fabricate Multi-Permselective Mixed Matrix Membranes. ACS APPLIED MATERIALS amp; INTERFACES. 2015. 7(9): 5528-5537. [8] Li Xueqin, Ma Lu,Zhang Haiyang, et al. Synergistic effect of combining carbon nanotubes and graphene oxide in mixed matrix membranes for efficient CO2 separation. JOURNAL OF MEMBRANE SCIENCE. 2015. 479: 1-10. [9] Xin Qingping, Li Zhao,Li Congdi, et al. Enhancing the CO2 separation performance of composite membranes by the incorporation of amino acid-functionalized graphene oxide. JOURNAL OF MATERIALS CHEMISTRY A. 2015. 3(12): 6629-6641. [10] Shen Yijia, Wang Huixian,Liu Jindun, et al. Enhanced Performance of a Novel Polyvinyl Amine/Chitosan/Graphene Oxide Mixed Matrix Membrane for CO2 Capture. ACS SUSTAINABLE CHEMISTRY amp; ENGINEERING. 2015. 3(8): 1819-1829. [11] Wang Luda, Drahushuk Lee W.,Cantley Lauren, et al. Molecular valves for controlling gas phase transport made from discrete angstrom-sized pores in graphene. NATURE NANOTECHNOLOGY. 2015. 10(9): 785. [12] Karunakaran M., Shevate R.,Kumar M., et al. CO2-selective PEO-PBT (PolyActive (TM))/graphene oxide composite membranes. CHEMICAL COMMUNICATIONS. 2015. 51(75): 14187-14190. [13] Li Xueqin, Wang Meidi,Wang Shaofei, et al. Constructing CO2 transport passageways in Matrimid (R) membranes using nanohydrogels for efficient carbon capture. JOURNAL OF MEMBRANE SCIENCE. 2015. 474: 156-166. [14] Hu Yaoxin, Wei Jing,Liang Yan, et al. Zeolitic Imidazolate Framework/Graphene Oxide Hybrid Nanosheets as Seeds for the Growth of Ultrathin Molecular Sieving Membranes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2016. 55(6): 2048-2052. [15] Shen Jie, Liu Gongping,Huang Kang, et al. Subnanometer Two-Dimensional Graphene Oxide Channels for Ultrafast Gas Sieving. ACS NANO. 2016. 10(3): 3398-3409.

3. 毕业设计（论文）进程安排

17.01.11~17.02.20 文献调研，开题报告 17.02.20~17.05.10 按时开展实验工作 17.05.10~17.05.28 中后期实验阶段及数据收集 17.05.28~17.06.10 数据整理，撰写论文